Multidimensional Isotropic Magnetic Shielding Contour Maps for the Visualization of Aromaticity in ortho-Arynes and Their Reactions

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چکیده

Abstract Visualization of electron delocalization and aromaticity in some selected arynes, including nonplanar examples, their Diels–Alder or dimerization reactions was achieved through multidimensional isotropic magnetic shielding contour maps. These maps showed that arynes are generally less aromatic than the corresponding arenes, peaks during when approaching transition state.

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ژورنال

عنوان ژورنال: Synthesis

سال: 2022

ISSN: ['1791-5155', '1791-5856']

DOI: https://doi.org/10.1055/a-1867-0674